Masters Theses

Author

Jung-He Wu

Date of Award

8-1990

Degree Type

Thesis

Degree Name

Master of Science

Major

Chemical Engineering

Major Professor

Marion G. Hansen

Committee Members

Donald C. Bogue, Frederick E. Weber, Raymond D. Krieg

Abstract

Extruded pipe is made by forcing a molten polymer through an annular die and cooling it; the final properties of the pipe depend on a number of variables, including in particular the cooling step, during which crystallization takes places. An accurate prediction of temperature profile and crystallinity distribution within a semi-crystalline polymer (polypropylene) is of importance in determining the processing conditions. In this study the solidification of the melt during cooling in pipe extrusion has been analyzed by means of a computer simulation. The mathematical model, which involves a steady-state nonlinear energy equation incorporating the crystallization kinetics proposed by Nakamura, simulates the behavior of polymer melt in the cooling chamber during formation of a thick walled pipe. An investigation was carried out into effects of melt inlet temperature, take-off speed, and pipe wall thickness on the temperature profile as well as crystallinity distribution. NACHOS II, a computer program based on finite element method designed for solution of two-dimensional fluid dynamics and heat transfer, is employed for the numerical solution. The numerical model gives therefore a basis for the prediction of the crystallinity distribution and adjustment of the operation conditions.

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