Masters Theses

Author

Guangyan Qin

Date of Award

8-1992

Degree Type

Thesis

Degree Name

Master of Science

Major

Environmental Engineering

Major Professor

Wayne T. Davis, Terry L. Miller

Committee Members

James Smoot

Abstract

In order to assess the importance of biogenic hydrocarbons on ozone formation in the lower atmosphere, photochemical simulations were carried out with a set of spatially resolved anthropogenic ozone precursors and countywide biogenic hydrocarbons emissions using EPA OZIPM-4 model. County-wide biogenic hydrocarbons (BHCs) emissions were calculated using the EPA PC-BEIS program. Results from the study show that BHC emissions accounted for 45% of the total VOC emissions in the study area. The contribution from BHCs to the total ozone loading was about 9%. The ozone standard was predicted to be attained by a 50% reduction in anthropogenic hydrocarbon emissions (AHCs) or a 50% reduction in NOx emissions or 30% reductions in both AHCs and NOx. Neither VOC nor NOx were found to be controlling but rather each tended to play an equal role in ozone formation. In the urban environment, BHCs in conjunction with urban NOx emissions were found to generate significant ozone levels even when anthropogenic emissions of VOCs were eliminated.

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