Doctoral Dissertations
Date of Award
8-2014
Degree Type
Dissertation
Degree Name
Doctor of Philosophy
Major
Mathematics
Major Professor
Tim P. Schulze
Committee Members
Ohannes Karakashian, Steven Wise, Yanfei Gao
Abstract
Kinetic Monte Carlo (KMC) uses random numbers to simulate the time evolution of processes with well-defined rates. We analyze a multi-step KMC algorithm aimed at speeding up the single-step procedure and apply the algorithm to study a model for the growth of a surface dendrite. The growth of the dendrite is initiated when atoms diffusing on a substrate cluster due to lower hopping rates for highly coordinated atoms. The boundary of the cluster is morphologically unstable when the flux of new atoms is supplied in the far field, a scenario that could be generated by masking a portion of a substrate that is subject to some kind of deposition process. We allow atoms far from the growing dendrite to take large hops while atoms near the dendrite follow a usual single-step KMC algorithm. We study how coarse-graining affects the distribution of waiting times for hops, and how to accurately couple the multi-step and single-step regions.
Recommended Citation
Clark, Holly Nichole Johnson, "Multistep Kinetic Monte Carlo. " PhD diss., University of Tennessee, 2014.
https://trace.tennessee.edu/utk_graddiss/2810