Doctoral Dissertations

Date of Award

5-2012

Degree Type

Dissertation

Degree Name

Doctor of Philosophy

Major

Physics

Major Professor

Joseph H. Macek

Committee Members

Predrag S. Krstic, Adolfo G. Eguiluz, Robert J. Harrison

Abstract

A key issue for the successful performance of current and future fusion reactors is understanding chemical and physical processes at the Plasma Material Interface (PMI). The material surfaces may be bombarded by plasma particles in a range of impact energies (1 eV - a few keV) and kept at a range of temperatures (300 - 1000 K). The dominant processes at the PMI are reflection and retention of impacting particles and sputtering (chemical and physical). Sputtering leads to surface erosion and pollution of the plasma, both of which degrade reactor performance. Retention influences the recycling of the plasma, and in the case of tritium, raises the question of radioactive waste. PMI is a multi-scale problem, ranging from timescales of femtoseconds to years and spatial scales between Angstroms to meters. The main goal of this dissertation is to model PMI processes at the nanometer/nanosecond scale using atomistic Molecular Dynamic (MD) approaches. In particular, simulations have been done on mixed amorphous materials: hydrogenated, lithiated, and oxygenated carbon; bombarded by H isotopes using Classical Molecular Dynamics (CMD) and a Quantum-Classical Molecular Dynamics (QCMD) approach.

Files over 3MB may be slow to open. For best results, right-click and select "save as..."

Share

COinS