Title
Computational Chemistry for Molecular Electronics
Document Type
Article
Publication Date
10-2003
Abstract
We present a synergetic effort of a group of theorists to characterize a molecular electronics device through a multiscale modeling approach. We combine electronic-structure calculations with molecular dynamics and Monte Carlo simulations to predict the structure of self-assembled molecular monolayers on a metal surface. We also develop a novel insight into molecular conductance, with a particular resolution of its fundamental channels, which stresses the importance of a complete molecular structure description of all components of the system, including the leads, the molecule, and their contacts. Both molecular dynamics and electron transport simulations imply that knowledge of detailed molecular structure and system geometry are critical for successful comparison with carefully performed experiments. We illustrate our findings with benzenedithiolate molecules in contact with gold.
Recommended Citation
Krstic ,P. S., Dean, D.J., Zhang, X. -G., Keffer, D. Leng, Y. S., Cummings, P.T., & J. C. Wells. (2003). Computational chemistry for molecular electronics. Computational Materials Science, 28(2), 321-341. DOI: 10.1016/S0927-0256(03)00116-2.