Masters Theses

Date of Award


Degree Type


Degree Name

Master of Science


Materials Science and Engineering

Major Professor

Claudia Rawn

Committee Members

Chuck Melcher, Narendra Dahotre


Single phase polycrystalline Li6Y(BO3)3:Ce has been produced with substitutions of Ca, Sc, La, Sr, Gd, and Lu substituting for Y. Samples included isotopes of 6-Li and 11-B through isotopically enriched Li2CO3 and H3BO3. X-ray powder diffraction was used to verify the phase(s) present, while Rietveld refinements provided lattice parameters. Photoluminescence data were collected to verify Ce activation and proper location within the crystal structure. The amount of Ce and Ca were then varied to survey the best composition for scintillation properties within Li6Y(BO3)3 based on results of pulse-height measurements. A single crystal of Li6Y0.8Ce0.1(BO3)3 was then grown using the Czochralski method which produced a boule weighing 38g.

Files over 3MB may be slow to open. For best results, right-click and select "save as..."