Date of Award


Degree Type


Degree Name

Doctor of Philosophy



Major Professor

George K. Schweitzer

Committee Members

David M. Jenkins, Laurence F. Miller, Jimmy W. Mays


Due to the shortage of 3He [helium-3], the goal of this project was to develop replacement materials for slow neutron detection in mixed radiation fields. The U.S. Department of Homeland Security (DHS) indicated that replacement materials should have an absolute neutron efficiency of 2.5 cps/ng of 252Cf (Californium-252) and a neutron/gamma discrimination intrinsic efficiency of 1 x 10-6 [one gamma-ray response in a million counts]. In this work, the use of amorphous lithium tetraborate (Li2B4O7:Ce) is analyzed as a thermal neutron detector. Also discussed is the synthesis of the lithium tetraborate, using 6Li [lithium-6], to form a crystalline powder that is heated simultaneously with cerium oxide (CeO2) and excess boric acid to produce an optically clear glass. In this study, the structure of glass was probed, the abnormal reduction of Ce4+ [tetravalent cerium] to Ce3+ [trivalent cerium] observed in the fluorescence peak at 360 nm, and irradiation studies with alpha particles, beta particles, gamma-rays, and neutrons were performed. The resulting material was shown to have a light yield of 550 photons/neutron, which is 8% the light output of GS-20, a lithiated glass.

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