Synthesis and Characterization of A-Site and B-Site Disordered High-Entropy Perovskites

Entropy-stabilized oxides are a new class of ceramic material inspired by high-entropy alloys. In entropy-stabilized oxides, many metallic elements in approximately equal amounts occupy one lattice site. The large number of atom types present in the crystal results in a high degree of disorder in the material. The purpose of this study was to determine if a single-phase samples of two entropy-stabilized oxides could be successfully created through solid-state synthesis. The first of these materials - (Gd0.2La0.2Nd0.2Sm0.2Y0.2)MnO3 - has has 5 A-site elements creating a high degree of disorder. The second of these materials - La(Co0.2Cr0.2Fe0.2Mn0.2Ni0.2)O3 - has 5 B-site elements creating a high degree of disorder. Successful synthesis of these two oxides proves that both sites of the perovskite structure can be used to create high-entropy oxides.